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|Section2= |Section3= |Section5= |Section7= |Section8= }} Sodium amide, commonly called sodamide, is the inorganic compound with the formula NaNH2. This solid, which is dangerously reactive toward water, is white, but commercial samples are typically gray due to the presence of small quantities of metallic iron from the manufacturing process. Such impurities do not usually affect the utility of the reagent. NaNH2 conducts electricity in the fused state, its conductance being similar to that of NaOH in a similar state. NaNH2 has been widely employed as a strong base in organic synthesis. ==Preparation and structure== Sodium amide can be prepared by the reaction of sodium with ammonia gas, but it is usually prepared by the reaction in liquid ammonia using iron(III) nitrate as a catalyst. The reaction is fastest at the boiling point of the ammonia, c. −33 °C. An electride, ()+e−, is formed as an intermediate. :2 Na + 2 NH3 → 2 NaNH2 + H2 NaNH2 is a salt-like material and as such, crystallizes as an infinite polymer. The geometry about sodium is tetrahedral. In ammonia, NaNH2 forms conductive solutions, consistent with the presence of Na(NH3)6+ and NH2− anions. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「sodium amide」の詳細全文を読む スポンサード リンク
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